Get Organic Synthesis Highlights v. 1 PDF

By Hans-Josef Altenbach, Hans-Ulrich Reißig, Karsten Krohn, Manfred Braun, Johann Mulzer

ISBN-10: 0895739186

ISBN-13: 9780895739186

ISBN-10: 1671741811

ISBN-13: 9781671741812

ISBN-10: 3527279555

ISBN-13: 9783527279555

This strange choice of forty nine essays offers an summary of the developments and accomplishments of artificial natural chemistry in recent times. detailed in its technique, it bargains with virtually each point of recent synthesis.

the 1st a part of the booklet describes tools and reagents, with specific emphasis on speedily constructing organometallic and biooriented strategies. within the moment half, those instruments are utilized to the syntheses of fascinating goal compounds and usual compounds with striking physiological homes. Mechanistic discussions and retrosynthetic analyses are incorporated. greater than one thousand updated references support the reader to pursue the themes highlighted right here.

This ebook provides either the lively researcher and the complex scholar perception into the aggressive surroundings, creativity, and resourcefulness so attribute of natural synthesis this present day

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Additional resources for Organic Synthesis Highlights v. 1

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J. Altenbach, M. Braun, K. -U. Reissig OVCH Verlagsgesellschaft mbH, 1991 Syntheses with Aliphatic Nitro Compounds There are two classic reagents that provide a carbanionic center immediately adjacent to a nitrogen atom: the cyanide anion and a deprotonated nitroalkane (f). It is the latter species that will be discussed in this chapter with respect to synthetic applications. Nitro compounds that have been deprotonated and subsequently treated with an electrophile (a) may be reduced to amines (b), or they may be converted into carbonyl compounds by a Nef reaction (c) [l].

108, 5908 (1986). [lo] E. J. Corey, L. 0. Weigel, A. R. Chamberlin, and B. Lipshutz, J. Am. Chem. 102, 1439 (1980). [ll] G. I. Tsuchihashi, S. Iriuchijma, and M. Ishibashi, Tetrahedron Lett. 1972, 4605. [12] R. R. Fraser, F. J. Schuber, and Y. Wi&eld, J. Am. Chem. 94, 8795 (1972). [13] C. Mioskowski and G. Solladie‘,Tetrahedron 36, 227 (19801 [14] For a review on chelation control see: M. Reetz, Angew. Chem. 96, 542 (1984); Angew. Chem. Int. , 23, 556 (1984). [l5] a) G. Solladik, G. Demailly, and C.

14] This book, page 300ff. [l5] D. Seebach and J. Zimmermann, Helv. Chim. Acta 69, 1147 (1986). [16] M. Demuth, A. -D. Sluma, A. K. Dey, C. -H. Tsay, Angew. Chem. 98, [17] [l8] [19] [20] [21] [22] [23] [24] [25] [26] [27] [28] [29] [30] 1093, Angew. Chem. Int. Ed. Engl. 25, 1117 (1986). M. Sato, K. Takayama, T. Furuya, N. Znukai, and C. Kaneko, Chem. Pharm. Bull. 35, 3971 (1987). H. -C. Cheng, J. Org. Chem. 52, 3178 (1987) and ref. cited. W. S. Johnson, Angew. Chem. 88, 33, Angew. Chem. Int. Ed.

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Organic Synthesis Highlights v. 1 by Hans-Josef Altenbach, Hans-Ulrich Reißig, Karsten Krohn, Manfred Braun, Johann Mulzer


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